Spectrophotometric determination of bismuth (III) with Methylthymol Blue

Spectrophotometric and derivative spectrophotometric determination of aluminium with Hydroxynaphthol Blue.

The reaction of aluminium(III) with Hydroxynaphtol Blue (HNB) in aqueous media at apparent pH 5.5 results in a red complex that is stable for at least 4 hr. Beer's Law is obeyed up to 1.6 microg/ml of aluminium(III) with an apparent molar absorptivity of 1.66 x 10(4) l.mol(-1). cm(-1) at 569 nm. This paper proposes procedures for aluminium(III) determination by ordinary and first-derivative spe...

Direct, selective flow injection spectrophotometric determination of calcium in wines using methylthymol blue and an on-line cascade dilution system

A flow-injection (FI) method is reported for the determination of calcium in wines using both offand on-line ‘cascade’ dilution FI systems. Methylthymol blue (MTB) was used as a colour agent and the absorbance of the coloured Ca–MTB complex produced was monitored at 610 nm. For both FI systems, the various chemical and physical variables were optimized and a study of interfering ions was also c...

Spectrophotometric determination of gallium(III) with rutin.

Spectrophotometric Determination of Nickel with Chlorophosphonazo-III

The optimum conditions for spectrophotometric method for the determination of Ni with chlorophosphonazo-III (CPA-III) were established and the nickel content in water samples has been successfully determined. In a pH 5.5 acetic acid-sodium acetate buffer medium, CPA-III and Ni formed a 1:3 green blue complex and the maximum absorption wavelength of the complex is at 620 nm. Ni content in a rang...

Kinetic Spectrophotometric Method for Determination of S032- Using Methylen blue

The present work reports a kinetic spectrophotometric method for the determination of traceamounts of sulphite that is based on inhibitory effect of sulphite on the oxidation of Methyleneblue (MB) in acidic media. The reaction is followed spectrophotometrically by monitoring thedecrease in absorbance of MB at 664 nm with a fixed time of 0.5-4.5 minutes. It was found thatsulphite exert a strong ...